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Öğe Impact of thickness on optoelectronic properties of ?-MoO3 film photodetectors: Integrating first-principles calculations with experimental analysis(Elsevier, 2023) Basyooni, Mohamed A.; Achehboune, Mohamed; Boukhoubza, Issam; Gaballah, A. E. H.; Tihtih, Mohammed; Belaid, Walid; En-nadir, RedouaneThis study focused on investigating the optoelectronic properties of molybdenum trioxide (alpha-MoO3) thin films using the atomic layer deposition (ALD) technique through different cycle numbers and theoretical investigation. Initial band gap calculations using standard DFT with GGA-PBE resulted in a value of 1.19 eV, which deviated significantly from experimental measurements. The GGA + U method with Hubbard U corrections was applied for the first time to improve the accuracy. This refinement led to a more precise band gap value of 3.09 eV, closely matching previously reported experimental data. The electronic parameters of the alpha-MoO3 photodetector, such as ideality factor (n), barrier height (phi 0), and series resistance (Rs), were analyzed using the thermionic emission theory and confirmed by Cheung and Nord's methods. The results demonstrated that the sample deposited with 100 pulses exhibited higher photodetector performance under UV illumination, despite having a lower Rs.Öğe Reduced graphene oxide-functionalized zinc oxide nanorods as promising nanocomposites for white light emitting diodes and reliable UV photodetection devices(Elsevier Science Sa, 2023) Boukhoubza, Issam; Derkaoui, Issam; Basyooni, Mohamed A.; Achehboune, Mohamed; Khenfouch, Mohammed; Belaid, Walid; Enculescu, MonicaWe present a breakthrough in the development of novel nanocomposites based on reduced graphene oxide (RGO)-functionalized zinc oxide (ZnO) nanorods that hold exceptional promise for their use in white light emitting diodes (LEDs) and reliable UV photodetection. The nanorods had a pristine hexagonal wurtzite struc-ture, as confirmed by XRD analysis. SEM images revealed sandwich-like nanocomposites with ZnO nanorods coated in reduced graphene oxide and embedded between two layers of RGO. The study also confirmed the hybridization and interactions between the layers using Raman measurements. The resulting nanocomposites displayed a lower band gap energy than ZnO and exhibited unique photoluminescence spectra with a white PL light. The photodetector based on RGO/ZnO/RGO sandwich structures demonstrated exceptional photoresponse, with higher photocurrent under UV illumination, making it highly promising for a wide range of optoelectronic applications. Overall, this study offers a novel and powerful approach to create nanocomposite structures with enhanced optical characteristics.