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Öğe Nanostructured MoS2 and WS2 Photoresponses under Gas Stimuli(Mdpi, 2022) Basyooni, Mohamed A.; Zaki, Shrouk E.; Alfryyan, Nada; Tihtih, Mohammed; Eker, Yasin Ramazan; Attia, Gamal F.; Yilmaz, MucahitThis study was on the optoelectronic properties of multilayered two-dimensional MoS2 and WS2 materials on a silicon substrate using sputtering physical vapor deposition (PVD) and chemical vapor deposition (CVD) techniques. For the first time, we report ultraviolet (UV) photoresponses under air, CO2, and O-2 environments at different flow rates. The electrical Hall effect measurement showed the existence of MoS2 (n-type)/Si (p-type) and WS2 (P-type)/Si (p-type) heterojunctions with a higher sheet carrier concentration of 5.50 x 10(5) cm(-2) for WS2 thin film. The IV electrical results revealed that WS2 is more reactive than MoS2 film under different gas stimuli. WS2 film showed high stability under different bias voltages, even at zero bias voltage, due to the noticeably good carrier mobility of 29.8 x 10(2) cm(2)/V. WS2 film indicated a fast rise/decay time of 0.23/0.21 s under air while a faster response of 0.190/0.10 s under a CO2 environment was observed. Additionally, the external quantum efficiency of WS2 revealed a remarkable enhancement in the CO2 environment of 1.62 x 10(8) compared to MoS2 film with 6.74 x 10(6). According to our findings, the presence of CO2 on the surface of WS2 improves such optoelectronic properties as photocurrent gain, photoresponsivity, external quantum efficiency, and detectivity. These results indicate potential applications of WS2 as a photodetector under gas stimuli for future optoelectronic applications.Öğe Role of oxygen vacancies in vanadium oxide and oxygen functional groups in graphene oxide for room temperature CO2 gas sensors(Elsevier Science Sa, 2019) Zaki, Shrouk E.; Basyooni, Mohamed A.; Shaban, Mohamed; Rabia, Mohamed; Eker, Yasin Ramazan; Attia, Gamal F.; Yilmaz, MucahitThe greenhouse effect is involving global heating and climate change within the world. Carbon dioxide (CO2) is one of the major gas at the origin of this effect, but also the byproduct of human activity. Therefore, monitoring the indoor/outdoor CO2 emission by gas sensors is one of the priorities for environmental preservation. In this paper, the sensing performance of CO2 towards two different O-rich films have been studied; graphene oxide (GO) and vanadium dioxide (VO2). The preparation of GO film has been carried out by spray pyrolysis on fluorine tin oxide (FTO) prepared by the modified Hummers method. While the VO2 film has been sol-gel spin-coated on a glass substrate. Both films have been characterized using XRD, SEM and electrical properties. The CO2 gas sensing mechanism and the role of oxygen vacancies in VO2 are addressing. The oxygen functional groups in GO play a main role in the CO2 gas the sensitivity level and response time. Their gas sensing performances have been investigated based on measuring the response vs recovery time, dynamic response curve analysis and sensitivity. In order to better understand the sensing mechanism, characterization has been done with different gas concentrations. Both GO and VO2 based CO2-sensors are acted as an n-type sensor. Sensing behavior of GO at RT has explained to be mainly mediated by the oxygen functional groups and a wide range of active sites. In the other hand, VO2 contains oxygen vacancies and more defect sites which play a main role in the RT sensing activity and low recovery time. (C) 2019 Elsevier B.V. All rights reserved.Öğe Self-Powered UV Photodetector Utilizing Plasmonic Hot Carriers in 2D ?-MoO3/Ir/Si Schottky Heterojunction Devices(Wiley-V C H Verlag Gmbh, 2024) Basyooni, Mohamed A.; Zaki, Shrouk E.; Tihtih, Mohammed; Boukhoubza, Issam; En-nadir, Redouane; Derkaoui, Issam; Attia, Gamal F.Self-powered UV sensing has enormous potential in military and civilian applications. However, achieving high responsivity and fast response/recovery time presents significant challenges. Self-powered photodetectors (PDs) have several advantages over traditional PDs, including higher sensitivity, lower power consumption, and simpler design. This study introduces a breakthrough self-powered PD that uses a Schottky junction of 2D alpha-MoO3/iridium (Ir)/Si ultrathin film to detect 365 nm light at 0 V bias through using atomic layer deposition (ALD) and sputtering systems. The PD response is enhanced by plasmonic Ir-induced hot carriers, enabling detection in a mere 0.1 ms. Incorporating a 4 nm Ir layer boosts the responsivity from 0 to 34 A W-1, and the external quantum efficiency is elevated from 0 to 7E11 under 365 nm light illumination. It also has a high I-ON/I-OFF ratio of 11.22E4 at 0 V. These results make the MoO3/4 nm Ir/Si structure an interesting option for self-powered PDs with high efficiency, and the use of a simple ALD system for large-scale fabrication of 2D alpha-MoO3 on hot carrier Ir plasmonic layer. The findings of this research hold tremendous promise in the field of UV sensing and can lead to exciting developments in military and civilian technology.