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Öğe Effect of Silica/Graphene Nanohybrid Particles on the Mechanical Properties of Epoxy Coatings(Springer Heidelberg, 2019) Ozcan, Umit Esra; Karabork, Fazliye; Yazman, Sakir; Akdemir, AhmetEpoxy resins are used as coating materials, but the practical use of epoxy coatings in industries is limited due to their weak mechanical properties. In the present paper, different amounts of silica nanoparticles (SiO2) and graphene nanoplatelets (GNPs) were introduced separately and together into an epoxy coating matrix as reinforcements. Graphene, a newly discovered carbon allotrope, has been found to improve the mechanical properties of the polymer composites in which it is dispersed. Silica particles are also known to improve the mechanical properties of composites. In this study, mechanical, physical and thermal properties of the epoxy coatings are considered as multidimensional by the macro- and microanalyses. The experimental results showed that after the addition of GNPs into the epoxy matrix, the flexibility and impact resistance of the coatings increased by 8.3 and 157.1%, respectively, in relation to neat epoxy. The microhardness increased by 53.8% and penetration depth, which is indicative of the scratch resistance, decreased by 29.7%, with the addition of SiO2-GNPs nanohybrid. A remarkable synergistic effect was observed between the GNPs and SiO2, which improved the hardness and the scratch resistance of the epoxy coatings.Öğe Effects of nano reinforcing/matrix interaction on chemical, thermal and mechanical properties of epoxy nanocomposites(Sage Publications Ltd, 2021) Yazman, Sakir; Uyaner, Mesut; Karabork, Fazliye; Akdemir, AhmetThis article investigates the impact of addition various types of nanoparticles with different structural, dimensional, and morphological properties on the interphase region formed between the particle/matrix and the curing behavior of the epoxy affect the nanocomposite material properties. For this purpose, epoxy nanocomposites (NCs) were produced by adding multi-walled carbon nanotube (MWCNT) and alumina (Al2O3) nanoparticles (NPs) into the epoxy matrix at different rates (0.5-2.0 wt.%). The effects of the particle/matrix interaction on the properties of the composite have been revealed by chemical, thermal, mechanical analyzes and microstructure investigations. An increase in the absorption density, which reveals the physical interaction of nanoparticles with the epoxy matrix, was observed in Fourier-transform infrared spectroscopy. Absorption vibration peak intensities in nanocomposite samples were at most 1.0 wt.% Al2O3 and 1.25 wt.% CNT added nanocomposites. It was observed that the T-g value increased depending on the number of nanoparticles. The addition of Al2O3 increased T-g values more than CNT. Besides, the mechanical properties of NCs were determined by tensile tests. The highest increase in mechanical properties was achieved by adding 1.25 wt.% CNT and 1.0 wt.% Al2O3, respectively. Mechanical properties tended to decrease at higher addition rates. The shape, size, amount, and distribution of nanoparticles added into the epoxy matrix directly affected the NCs' properties. It has been determined that homogeneously dispersed spherical Al2O3 nanoparticles are more effective than fiber-shaped CNTs in the properties of NCs.Öğe Improvement of anti-corrosion performance (surface and near the cut edge) and mechanical properties of epoxy coatings modified with nano, micro and hybrid ZnO particles(Sage Publications Ltd, 2023) Kabaoglu, Emre; Karabork, Fazliye; Balun Kayan, Didem; Akdemir, AhmetComposites were formed by incorporating nano, micro and hybrid-ZnO particles into the epoxy matrix at the same loading levels (3%) and applied at 90 mu m thickness on the galvanized steel substrate using a film applicator in this study. The improvement in anti-corrosion performance and mechanical and physical properties of the composite coatings were evaluated using various tests and techniques such as salt-spray, electrochemical impedance spectroscopy, nanohardness, microscratch, cross-cut, bending, Fourier transform infrared spectroscopy, thermogravimetric and Scanning electron microscopy. The corrosion performance of the composite coatings near the cut edge is discussed in detail as well as on the surface of galvanized steel. The results show that the addition of all ZnO particles has a positive effect on the corrosion resistance and mechanical properties of the coatings. The addition of nano, micro and hybrid ZnO particles increased the hardness of the composites by 52, 37 and 56%, respectively, compared to the neat epoxy. Although the cathodic protection performance is weakened near the cut edge due to the loss of Zn after thermal cutting, high barrier protection was provided with composite coatings, especially micro ZnO/Epoxy composite coating.Öğe Investigation Effect of Zinc Nanoparticles on The Mechanical and Anticorrosion Properties of Epoxy Coatings on Stainless Steel Surface(Gazi Univ, 2021) Apsak, Merve; Akdemir, Ahmet; Karabork, Fazliye; Yazman, SakirIn this study, effects of zinc nanoparticles (ZNPs) on the mechanical properties of epoxy coatings and anticorrosion behavior on the stainless steel were investigated. The nanocomposites (NCs) were obtained by adding ZNPs (0.5, 1.0, 1.5 wt%) to epoxy resin. The first stage in this study, bulk samples were prepared for tensile test and DSC, TGA, FTIR, SEM analysis. The test and analysis were performed separately for samples cured at room temperature for 24 h and postcured at 80 degrees C for 15 h in the oven. The results indicated that both postcuring and adding ZNPs caused an increase in the mechanical properties of the epoxy matrix. Tensile strength increased by 13.2% and 90.2% in the postcured NC (1.0% Zn) and untreated NC (0.5% Zn) respectively. The NCs prepared with the same parameters for the second stage were coated on AISI 304 test panels and the panels were postcured in the oven. The anticorrosive performance of the coatings was studied by an immersion test. According to the corrosion test results, it was observed that the coated steel surface preserves the best rate of 1.0% ZNPs containing epoxy composite. In addition, impact resistance, flexibilities and adhesion properties of the coating were analyzed.