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Öğe Analytical Review of Geopolymer Concrete: Retrospective and Current Issues(Mdpi, 2023) Meskhi, Besarion; Beskopylny, Alexey N.; Stel'makh, Sergey A.; Shcherban, Evgenii M.; Mailyan, Levon R.; Shilov, Alexandr A.; El'shaeva, DianaThe concept of sustainable development provides for the search for environmentally friendly alternatives to traditional materials and technologies that would reduce the amount of CO2 emissions into the atmosphere, do not pollute the environment, and reduce energy costs and the cost of production processes. These technologies include the production of geopolymer concretes. The purpose of the study was a detailed in-depth analytical review of studies of the processes of structure formation and properties of geopolymer concretes in retrospect and the current state of the issue. Geopolymer concrete is a suitable, environmentally friendly and sustainable alternative to concrete based on ordinary Portland cement (OPC) with higher strength and deformation properties due to its more stable and denser aluminosilicate spatial microstructure. The properties and durability of geopolymer concretes depend on the composition of the mixture and the proportions of its components. A review of the mechanisms of structure formation, the main directions for the selection of compositions and processes of polymerization of geopolymer concretes has been made. The technologies of combined selection of the composition of geopolymer concrete, production of nanomodified geopolymer concrete, 3D printing of building structures from geopolymer concrete, and monitoring the state of structures using self-sensitive geopolymer concrete are considered. Geopolymer concrete with the optimal ratio of activator and binder has the best properties. Geopolymer concretes with partial replacement of OPC with aluminosilicate binder have a denser and more compact microstructure due to the formation of a large amount of calcium silicate hydrate, which provides improved strength, durability, less shrinkage, porosity and water absorption. An assessment of the potential reduction in greenhouse gas emissions from the production of geopolymer concrete compared to the production of OPC has been made. The potential of using geopolymer concretes in construction practice is assessed in detail.Öğe Composition Component Influence on Concrete Properties with the Additive of Rubber Tree Seed Shells(Mdpi, 2022) Beskopylny, Alexey N.; Shcherban, Evgenii M.; Stel'makh, Sergey A.; Meskhi, Besarion; Shilov, Alexandr A.; Varavka, Valery; Evtushenko, AlexandrThe growth in the volume of modern construction and the manufacture of reinforced concrete structures (RCSs) presents the goal of reducing the cost of building materials without compromising structures and opens questions about the use of environmentally friendly natural raw materials as a local or full replacement of traditional mineral components. This can also solve the actual problem of disposal of unclaimed agricultural waste, the features of which may be of interest to the construction industry. This research aimed to analyze the influence of preparation factors on concrete features with partial substitution of coarse aggregate (CA) with rubber tree (RT) seed shells and to determine the optimal composition that can make it possible to attain concrete with improved strength features. CA was replaced by volume with RT seed shells in an amount from 2% to 16% in 2% increments. Scanning electronic microscopy was employed to investigate the structure of the obtained concrete examples. The maximum increase in strength features was observed when replacing coarse filler with 4% RT seed shell by volume and amounted to, for compressive and axial compressive strength (CS) and tensile and axial tensile strength (TS) in twisting, 6% and 8%, respectively. The decrease in strain features under axial compression and under axial tension was 6% and 5%, respectively. The modulus of elasticity increased to 7%. The microstructure of hardened concrete samples with partial replacement of CA with RT seed shells in the amount of 2%, 4% and 6% was the densest with the least amount of pores and microcracks in comparison with the structure of the sample of the control composition, as well as samples with the replacement of CA with RT seed shells in an amount of more than 6%. The expedient effective replacement of CA with RT shells led to a reduction in battered stone of up to 8%.Öğe Normal-Weight Concrete with Improved Stress-Strain Characteristics Reinforced with Dispersed Coconut Fibers(Mdpi, 2022) Shcherban', Evgenii M.; Stel'makh, Sergey A.; Beskopylny, Alexey N.; Mailyan, Levon R.; Meskhi, Besarion; Shilov, Alexandr A.; Chernil'nik, AndreiAccording to the sustainable development concept, it is necessary to solve the issue of replacing fiber from synthetic materials with natural, environmentally friendly, and cheap-to-manufacture renewable resources and agricultural waste. Concrete is the primary material for which fibers are intended. Therefore, the use of vegetable waste in concrete is an essential and urgent task. Coconut fiber has attracted attention in this matter, which is a by-product of the processing of coconuts and makes it relevant. This work aims to investigate the experimental base for the strength properties of dispersed fiber-reinforced concrete with coconut fibers, as well as the influence of the fiber percentage on the mechanical, physical, and deformation characteristics. The samples were made of concrete with a compressive strength at 28 days from 40 to 50 MPa. The main mechanical characteristics such as strength in compression (cubic and prismatic) and tension (axial and bending), as well as the material's compressive and tensile strains, were investigated. The percentage of reinforcement with coconut fibers was taken in the range of 0% to 2.5% with an increment of 0.25 wt.%. Tests were carried out 28 days after the manufacture. The microstructure of the resulting compositions was investigating using the electron microscopy method. The most rational percentage of coconut fibers was obtained at 1.75%. The increase in mechanical indicators was 24% and 26% for compression and axial compression, respectively, and 42% and 43% for tensile bending and axial tension, respectively. The ultimate strains in compression were raised by 46% and in tension by 51%. The elastic modulus was increased by 16%.Öğe Physical, Mechanical and Structural Characteristics of Sulfur Concrete with Bitumen Modified Sulfur and Fly Ash(Mdpi, 2023) Stel'makh, Sergey A.; Shcherban', Evgenii M.; Beskopylny, Alexey N.; Mailyan, Levon R.; Meskhi, Besarion; Shilov, Alexandr A.; Evtushenko, AlexandrIndustrial waste usage in the technology of construction materials is currently in a relevant and promising direction. Materials made of industrial waste have a lower cost and are highly environmentally friendly. The objective of this study is to develop effective compositions of sulfur concrete based on the maximum possible number of various wastes of the local industry for this and to investigate the characteristics of this composite. Test samples of sulfur concrete were made from sulfur, fly ash, mineral aggregates and bitumen additive. The dosages of fly ash, sand and bitumen varied, while the content of sulfur and crushed stone remained constant. The following main characteristics of sulfur concrete were determined: density; compressive strength; and water absorption. Tests of sulfur concrete were carried out after 1 day and 28 days of hardening. The best values of compressive strength (24.8 MPa) and water absorption (0.9%) were recorded for the composition of sulfur concrete at the age of 28 days with the following content of components: sulfur-25%, modified with 4% bitumen of its mass; fly ash-10%; crushed stone-40%; and sand-25%. The optimal composition of modified sulfur concrete showed compressive strength up to 78% more and water absorption up to 53% less than the control composition. The characteristics of the sulfur concrete samples after 28 days of hardening differ slightly from the values after 1 day of hardening (up to 1.8%). An analysis of the structure confirmed the effectiveness of the developed composition of sulfur concrete in comparison with the control.