Sustainable and efficient removal of cationic, anionic and neutral dyes from water by pre-deposited vinasse biochar membrane

dc.contributor.authorKazak, Omer
dc.contributor.authorAkkaya, Gulizar Kurtoglu
dc.contributor.authorTor, Ali
dc.date.accessioned2024-02-23T14:12:46Z
dc.date.available2024-02-23T14:12:46Z
dc.date.issued2023
dc.departmentNEÜen_US
dc.description.abstractThis study demonstrated a simple and sustainable approach for removing dyes from water through a new predeposited vinasse biochar (PDVB) membrane, which was developed by single-step deposition of vinasse biochar powder on a filter paper support via vacuum pumping. The PDVB membrane combined advantages of adsorption and membrane filtration processes in one-stage. Performance of the PDVB membranes with waterwettable surface was examined on methylene blue (as a model dye) solution as functions of pyrolysis temperature, amount of biochar on the membrane unit area, solution pH, initial concentration and temperature of dye solution in a dead-end filtration mode. The best performance (removal efficiency >99%, flux: 8017 L/(m2.h)) was obtained at a wide pH range (2-11) by using membrane (7.95 mg biochar/cm2, derived from pyrolysis of vinasse at 900 degrees C). Moreover, initial dye concentration and solution temperature had no considerable effect on membrane performance, which was stable even after ten cycles of filtration-regeneration by ethanol-washing. At pH 2, the membrane was also quite good at removing Congo red (anionic dye) with efficiency of 98%, which decreased when increasing pH from 2 to 11. Behavior of membrane towards dyes with different characteristics was explained by considering high surface area (756 m2/g) of the biochar and phenomenon, including aromatic stacking and electrostatic-attraction between dye molecule and biochar surface. All findings and application to a real textile industry effluent demonstrated that developed membrane was easy-to-use and sustainable material for effective treatment of water and wastewater containing dyes with different molecular weights and ionic characteristics.en_US
dc.identifier.doi10.1016/j.jece.2023.110042
dc.identifier.issn2213-2929
dc.identifier.issn2213-3437
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-85158828175en_US
dc.identifier.urihttps://doi.org/10.1016/j.jece.2023.110042
dc.identifier.urihttps://hdl.handle.net/20.500.12452/12172
dc.identifier.volume11en_US
dc.identifier.wosWOS:001041658000001en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Sci Ltden_US
dc.relation.ispartofJournal Of Environmental Chemical Engineeringen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectVinasseen_US
dc.subjectBiocharen_US
dc.subjectMembraneen_US
dc.subjectSustainable Water Treatmenten_US
dc.subjectDye Removalen_US
dc.titleSustainable and efficient removal of cationic, anionic and neutral dyes from water by pre-deposited vinasse biochar membraneen_US
dc.typeArticleen_US

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