Electrochromic properties of a polydithienylpyrrole derivative with N-phenyl pyrrole subunit
dc.authorid | Buket Bezgin Carbas: 0000-0002-4178-5911 | en_US |
dc.authorid | Nurseli Mislina Ergin: 0000-0002-9653-5047 | en_US |
dc.authorid | Hüseyin Bekir Yıldız: 0000-0003-1123-8797 | en_US |
dc.authorid | Arif Kıvrak: 0000-0003-4770-2686 | en_US |
dc.authorid | Atıf Emre Demet: 0000-0002-7401-9455 | en_US |
dc.contributor.author | Bezgin Carbas, Buket | |
dc.contributor.author | Ergin, Nurseli Mislina | |
dc.contributor.author | Yıldız, Hüseyin Bekir | |
dc.contributor.author | Kıvrak, Arif | |
dc.contributor.author | Demet, Atıf Emre | |
dc.date.accessioned | 2023-02-08T07:01:38Z | |
dc.date.available | 2023-02-08T07:01:38Z | |
dc.date.issued | 2023 | en_US |
dc.department | NEÜ, Mühendislik-Mimarlık Fakültesi, Enerji Sistemleri Mühendisliği Bölümü | en_US |
dc.description | Makale | en_US |
dc.description | WOS:000879334800006 | en_US |
dc.description.abstract | In this report, a new N-phenyl typed 2,5-dithienyl pyrrole compound bearing pyrrole unit was successfully synthesized and its conjugated homopolymer, poly(1-(4-(1H-pyrrol-1-yl)phenyl)-2,5-di(thiophen-2-yl)-1H-pyrrole) (P(SNS-Ph-Pyr)), was obtained in the medium of 0.1 M TBAPF(6)/DCM via electroanalytical methods. Cyclic voltammetry and FTIR studies proved that monomer SNS-Ph-Pyr was synthesized and polymerized electrochemically and its corresponding polymer film, P(SNS-Ph-Pyr)) has a well reversible redox peaks at about 0.70/ 0.50 V vs. Ag/AgCl reference electrode in monomer free solution with a long term reversible redox behavior. The in situ UV-visible spectroelectrochemical studies of polymer film exhibited that electrochromic P(SNS-Ph-Pyr)) film had a color transition between yellow (at reduced state (0.0 V)) to grayish blue (at oxidized state (1.0 V)) with a intermediate color (green at 0.70 V). Moreover, electrochromic switching studies displayed that polymer film (coated with a thickness of 100 mC/cm(2)) had average optical contrast values (15.6% (383 nm), 19.5% (650 nm) and 41.7% (900 nm) but high coloration efficiency values (220 cm(2)/C (383 nm), 264 cm(2)/C (650 nm) and 384 cm(2)/C (900 nm). | en_US |
dc.description.sponsorship | Scientific and Technological Research Council of Türkiye (TUBITAK) | en_US |
dc.identifier.citation | Bezgin Carbas, B., Ergin, N. M., Yıldız, H. B., Kıvrak, A., Demet, A. E. (2023). Electrochromic properties of a polydithienylpyrrole derivative with N-phenyl pyrrole subunit. Materials Chemistry and Physics, 293, 1-9. | en_US |
dc.identifier.doi | 10.1016/j.matchemphys.2022.126916 | en_US |
dc.identifier.endpage | 9 | en_US |
dc.identifier.issn | 0254-0584 | en_US |
dc.identifier.issn | 1879-3312 | en_US |
dc.identifier.issue | - | en_US |
dc.identifier.scopusquality | Q1 | en_US |
dc.identifier.startpage | 1 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1016/j.matchemphys.2022.126916 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12452/9173 | |
dc.identifier.volume | 293 | en_US |
dc.identifier.wos | WOS:000879334800006 | en_US |
dc.identifier.wosquality | Q2 | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.publisher | Elsevier | en_US |
dc.relation.ispartof | Materials Chemistry and Physics | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Başka Kurum Yazarı | en_US |
dc.relation.tubitak | 121G114 | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | 2,5-dithienylpyrrole | en_US |
dc.subject | Conjugated Polymer | en_US |
dc.subject | Electrochromic Polymer | en_US |
dc.subject | Poly(2,5-dithienylpyrrole) | en_US |
dc.title | Electrochromic properties of a polydithienylpyrrole derivative with N-phenyl pyrrole subunit | en_US |
dc.type | Article | en_US |
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