Characteristics and mechanisms for highly efficient adsorption of Pb(II) from aqueous solutions by engineered vinasse biochar with cold oxygen plasma process
Küçük Resim Yok
Tarih
2022
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Science Sa
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Vinasse based biochar was engineered by cold oxygen plasma for different treatment time between 1 and 10 min to obtain highly efficient adsorbent for Pb(II) in the aqueous solutions. The engineered biochar with largest surface area (307 m(2)/g) and primarily microporous structure was achieved when cold oxygen plasma is processed for 3 min, providing the highest adsorption capacity (481 mg/g) derived from 500 mg/L of Pb(II) solution. For the equilibrium time (90 min) and the favorite solution pH (5.0), the best-fitting isotherm model was Langmuir isotherm one with Q(o) (714 mg/g), which is superior to those of many biochar based Pb(II) adsorbents in the literature. On the basis of XRD, XPS, FT-IR instruments and surface charge measurements, the adsorption mechanisms included ion-exchange, precipitation, electrostatic attraction, cation-pi interaction and complexation. The reusable engineered vinasse biochar has also applicability to real water samples without matrix effects.
Açıklama
Anahtar Kelimeler
Vinasse, Biochar, Oxygen Plasma, Lead Adsorption, Adsorption Mechanism
Kaynak
Chemical Engineering And Processing-Process Intensification
WoS Q Değeri
Q2
Scopus Q Değeri
Q1
Cilt
171
