Palladium nanoparticles supported on cobalt(II,III) oxide nanocatalyst: High reusability and outstanding catalytic activity in hydrolytic dehydrogenation of ammonia borane

Basit Öğe Kaydı
dc.contributor.authorAkbayrak, Serdar
dc.contributor.authoroezkar, Saim
dc.date.accessioned2024-02-23T14:12:35Z
dc.date.available2024-02-23T14:12:35Z
dc.date.issued2022
dc.departmentNEÜen_US
dc.description.abstractA new palladium(0) nanocatalyst is developed to enhance the catalytic efficiency of precious metal catalysts in hydrogen generation from the hydrolytic dehydrogenation of ammonia borane. Magnetically separable Pd-0/Co3O4 nanocatalyst can readily be obtained by the reduction of palladium(II) cations impregnated on cobalt(II, III) oxide at room temperature. The obtained Pd-0/Co3O4 nanocatalyst with 0.25% wt. palladium loading has outstanding catalytic activity with a record turnover frequency of 3048 min(-1) in the releasing H-2 from the hydrolysis of ammonia borane at 25.0 degrees C. They also provide out-standing reusability even after the tenth run of the hydrolysis of ammonia borane at 25.0 degrees. The high activity and superb stability of magnetically isolable Pd-0/Co3O4 nanoparticles are attributed to the favor-able interaction of palladium with the surface of reducible cobalt oxide. (C) 2022 Elsevier Inc. All rights reserved.en_US
dc.description.sponsorshipResearch Fund of the Necmettin Erbakan University [2112MER03003, 221219006]; Turkish Academy of Sciences and Turkish Academy of Sciences for Outstanding Young Scientists Awards [TUBA-GEBIP]en_US
dc.description.sponsorshipThis work was supported by Research Fund of the Necmettin Erbakan University, Project Numbers: 2112MER03003, 221219006. Partial support by Turkish Academy of Sciences and Turkish Academy of Sciences for Outstanding Young Scientists Awards (TUBA-GEBIP) is gratefully acknowledged.en_US
dc.identifier.doi10.1016/j.jcis.2022.06.135
dc.identifier.endpage758en_US
dc.identifier.issn0021-9797
dc.identifier.issn1095-7103
dc.identifier.pmid35820210en_US
dc.identifier.scopus2-s2.0-85134428721en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage752en_US
dc.identifier.urihttps://doi.org/10.1016/j.jcis.2022.06.135
dc.identifier.urihttps://hdl.handle.net/20.500.12452/12119
dc.identifier.volume626en_US
dc.identifier.wosWOS:000829364200014en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherAcademic Press Inc Elsevier Scienceen_US
dc.relation.ispartofJournal Of Colloid And Interface Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPalladium Nanoparticlesen_US
dc.subjectCobalt(Ii,Iii) Oxideen_US
dc.subjectMagnetic Nanocatalysten_US
dc.subjectDehydrogenationen_US
dc.subjectAmmonia Boraneen_US
dc.titlePalladium nanoparticles supported on cobalt(II,III) oxide nanocatalyst: High reusability and outstanding catalytic activity in hydrolytic dehydrogenation of ammonia boraneen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
PubMed İndeksli Yayın Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu