Self-assembly of a new building block of {BMo12O40} with excellent catalytic activity for methylene blue

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dc.contributor.authorFindik, Mukerrem
dc.contributor.authorUcar, Asuman
dc.contributor.authorColak, Alper Tolga
dc.contributor.authorSahin, Onur
dc.contributor.authorBingol, Haluk
dc.contributor.authorSayin, Ulku
dc.contributor.authorKocak, Nuriye
dc.date.accessioned2024-02-23T14:13:36Z
dc.date.available2024-02-23T14:13:36Z
dc.date.issued2019
dc.departmentNEÜen_US
dc.description.abstractA novel organic-inorganic hybrid of 2,2'-bipyridyl (2,2'-bipy) linked covalently with the first inorganic framework based on boron-containing Keggin-type heteropolymolybdate anion [BMo12O40](5-) has been hydrothermally synthesized in aqueous solution. The crystal structure was fully characterized by elemental analyses, single crystal X-ray diffraction, Fourier-transform infrared spectrum (FT-IR), powder X-ray diffraction (XRD), Ultraviolet-visible spectroscopy (UV-Vis) and electron paramagnetic resonance (EPR) analysis. The catalytic performance of the synthesized catalyst was studied in degradation of methylene blue (MB) at ambient temperature. The catalyst exhibited excellent degradation against MB with a rate constant of 0.506/m, which was much higher than those by other polyoxometalate catalysts. Moreover, it was found to be easily separated from the reaction solution and recycled up to five times without significant loss of degradation activity. (C) 2019 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipNecmettin Erbakan University Research Foundation [151210002]en_US
dc.description.sponsorshipThe authors thank the Necmettin Erbakan University Research Foundation (151210002) for the financial support of this study. The authors acknowledge Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer.en_US
dc.identifier.doi10.1016/j.poly.2018.12.043
dc.identifier.endpage237en_US
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-85060091565en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage229en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2018.12.043
dc.identifier.urihttps://hdl.handle.net/20.500.12452/12497
dc.identifier.volume160en_US
dc.identifier.wosWOS:000459518800030en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPolymcometalateen_US
dc.subjectHeteropolymolybdateen_US
dc.subjectCatalytic Degradationen_US
dc.subjectMethylene Blueen_US
dc.subjectSingle Crystal Structureen_US
dc.titleSelf-assembly of a new building block of {BMo12O40} with excellent catalytic activity for methylene blueen_US
dc.typeArticleen_US

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