Fabrication and characterization of calix[4]arene Langmuir-Blodgett thin film for gas sensing applications

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dc.contributor.authorAcikbas, Yaser
dc.contributor.authorBozkurt, Selahattin
dc.contributor.authorHalay, Erkan
dc.contributor.authorCapan, Rifat
dc.contributor.authorGuloglu, Mehmet Levent
dc.contributor.authorSirit, Abdulkadir
dc.contributor.authorErdogan, Matem
dc.date.accessioned2024-02-23T13:56:12Z
dc.date.available2024-02-23T13:56:12Z
dc.date.issued2017
dc.departmentNEÜen_US
dc.description.abstractIn this work, the Langmuir-Blodgett (LB) technique was applied onto the different substrates such as quartz, quartz crystals and gold coated glass for fabricating LB thin films with 25,27-(Dipropylmorpholinoacetamido)-26,28-dihydroxycalix[4]arene. The characteristics of the calix[4]arene LB films were evaluated by UV-Vis, atomic force microscopy (AFM), quartz crystal microbalance (QCM) and surface plasmon resonance (SPR) measurements. The mass deposited on the quartz crystal per bilayer was predicted as 2028.80 ng (7.65 ng mm(-2)) for the calix[4]arene LB film. The sensing abilities of this LB film towards the development of room temperature organic vapor sensing devices were also examined. QCM and SPR systems were fixed to investigate vapor sensing performance of macrocyclic LB films during exposure to volatile organic compounds (VOCs). The macrocyclic LB thin films were more sensitive to dichloromethane than other vapors. The sensitivity and detection limit values of the calix[4]arene QCM sensor to dichloromethane vapor were calculated as 2.023 Hz ppm(-1) and 1.482 ppm, respectively. The sensitivities of the calix[4]arene LB films against organic vapors can be explained with the host-guest interaction between the cavity of molecule and the organic vapor molecules. It is determined that the calix[4]arene LB film is more sensitive to dichloromethane than other vapors at room temperature and the calix[4]arene is a promising material serving as a vapor sensing device.en_US
dc.description.sponsorshipResearch Foundation of Usak University [UBAP 2017/HD-MF001]; Usak University Scientific Analysis Technological Application and Research Center (UBATAM)en_US
dc.description.sponsorshipThis work was supported by the Research Foundation of Usak University (UBAP 2017/HD-MF001). We also thank Usak University Scientific Analysis Technological Application and Research Center (UBATAM) for their support.en_US
dc.identifier.doi10.1007/s10847-017-0732-6
dc.identifier.endpage84en_US
dc.identifier.issn1388-3127
dc.identifier.issn1573-1111
dc.identifier.issue1.Şuben_US
dc.identifier.scopus2-s2.0-85029636769en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage77en_US
dc.identifier.urihttps://doi.org/10.1007/s10847-017-0732-6
dc.identifier.urihttps://hdl.handle.net/20.500.12452/11125
dc.identifier.volume89en_US
dc.identifier.wosWOS:000411121500007en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal Of Inclusion Phenomena And Macrocyclic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectLangmuir-Blodgett Filmsen_US
dc.subjectChemical Sensorsen_US
dc.subjectCalix[4]Areneen_US
dc.subjectQcmen_US
dc.subjectSpren_US
dc.titleFabrication and characterization of calix[4]arene Langmuir-Blodgett thin film for gas sensing applicationsen_US
dc.typeArticleen_US

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