Simple and effective removal of psychiatric pharmaceuticals from wastewater treatment plant effluents by magnetite red mud nanoparticles
Küçük Resim Yok
Tarih
2021
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Psychological disorders due to the COVID-19 pandemic have increased the consumption of psychiatric pharmaceuticals on a global scale in last year. These compounds reach wastewater treatment plants (WWTP) through sewerage system and are not sufficiently removed by using conventional treatment process. Psychiatric drugs released with WWTP effluent may cause possible risks to the receiving aquatic environment. Also, two antidepressants have been included in the watch list in 2020. Therefore, simple and relatively cost effective removal of psychiatric drugs from wastewaters becomes important. Magnetite red mud nanoparticles (RM-NPs) synthesized was applied for the removal of psychiatric drugs (fluoxetine, paroxetine, carbamazepine, diazepam, and lorazepam) in WWTP effluent first time in this study. The adsorption of carbamazepine as a model compound was fitted well with pseudo-second-order kinetic model. The Freundlich isotherm model better represented the sorption data than the Langmuir model. High adsorption capacity (90.5 mg/g) was reached at 30 min contact time at pH 6.5-7.0 at 25 degrees C. The adsorption rate was described by the pseudo second order model and its rate control mechanism was controlled by film diffusion. The magnetite RM-NPs were efficiently used for the removal of carbamazepine from real WWTP effluents. The adsorption capacity and the magnetic separability of the regenerated magnetite RM-NPs were unaffected five cycles. Due to its simple application, low cost and high adsorption capacity, magnetite RM-NPs can be recommended as a better adsorbent comparing to commercial adsorbents to remove psychiatric drugs from WWTP effluents. (c) 2021 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
Magnetic Nanoparticles, Psychiatric Pharmaceuticals, Red Mud, Wastewater
Kaynak
Science Of The Total Environment
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
784
