Optical and Vapor Sensing Properties of Calix[4]arene Langmuir-Blodgett Thin Films with Host-Guest Principles
Küçük Resim Yok
Tarih
2018
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Taylor & Francis Inc
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
25,27-(Dipropylmorpholinoacetamido)-26,28-dihydroxycalix[4]arene was used as a chemical sensor material in this work. The calix[4]arene LB thin films were prepared onto a gold-coated glass and quartz glass substrates to fabricate a thin film chemical sensor element. Atomic Force Microscopy (AFM) and Surface Plasmon Resonance (SPR) techniques were used to characterize all the calix[4]arene LB thin films. The film thickness and the refractive index of thin films can be evaluated with the fitted experimental SPR datas. The refractive index and the thickness per monolayer of LB films were determined as a 1.58 +/- 0.04 and 1.27 +/- 0.09nm, respectively. The calix[4]arene LB thin film chemical sensor element was exposed to dichloromethane, chloroform, benzene and toluene vapors. The SPR kinetic measurements displayed that, the photodetector response change, I-rf for saturated dichloromethane vapor is much larger than the other vapors with the I-rf value of 48 au and the diffusion coefficient value of 5.1 x 10(-16) cm(2)s(-1). Swelling process was analyzed by well known Fick's Equations. In this approach diffusion coefficients for swelling were conformed to the square root of time and were correlated with the volatile organic compounds. Our results showed that calix[4]arene thin film has a highly selective with a large response to dichloromethane vapor.
Açıklama
Anahtar Kelimeler
Calix[4]Arene, Swelling, Surface Plasmon Resonance, Organic Vapor, Lb Thin Film
Kaynak
Journal Of Macromolecular Science Part A-Pure And Applied Chemistry
WoS Q Değeri
Q4
Scopus Q Değeri
Q2
Cilt
55
Sayı
7
