Magnetically separable nickel ferrite supported palladium nanoparticles: Highly reusable catalyst in Sonogashira cross-coupling reaction

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dc.contributor.authorKeskin, Selbi
dc.contributor.authorCitlakoglu, Meryem
dc.contributor.authorAkbayrak, Serdar
dc.contributor.authorKaya, Serdal
dc.date.accessioned2024-02-23T14:12:35Z
dc.date.available2024-02-23T14:12:35Z
dc.date.issued2022
dc.departmentNEÜen_US
dc.description.abstractThere is an increasing attention in developing highly efficient and reusable palladium-based catalysts used for the coupling reactions due to the high cost of palladium metal salts. Magnetically separable palladium nanoparticles have a high potential to be used as catalysts in numerous organic reactions due to their facile separation from the reaction medium by an external magnet. Herein, NiFe2O4 supported palladium nanoparticles (Pd/NiFe2O4) were successfully prepared by impregnation and reduction method in water and used as catalysts for Sonogashira cross-coupling reactions. Magnetically separable Pd/NiFe2O4 catalysts were found to be highly active and reusable in this reaction. Pd/NiFe2O4 provided an outstanding turnover frequency value (106.4 h(-1)) in the reaction between phenylacetylene and iodobenzene in ethanol at 70 degrees C and it was also found to be highly active in the water. Magnetically separable Pd/ NiFe2O4 exhibited high catalytic performance even after the tenth use in this reaction. (C) 2022 Elsevier Inc. All rights reserved.en_US
dc.description.sponsorshipResearch Fund of the Necmettin Erbakan University [2112MER03003, 221219006, 2020MER03002]; Turkish Acedemy of Sciences for Outstanding Young Scientists Award (TUBA-GEB_IP)en_US
dc.description.sponsorshipThis work supported by Research Fund of the Necmettin Erbakan University, Project Numbers: 2112MER03003, 221219006, 2020MER03002. Partial support by Turkish Acedemy of Sciences for Outstanding Young Scientists Award (TUBA-GEB_IP) is gratefully acknowledged.en_US
dc.identifier.doi10.1016/j.jcis.2022.05.056
dc.identifier.endpage583en_US
dc.identifier.issn0021-9797
dc.identifier.issn1095-7103
dc.identifier.pmid35598486en_US
dc.identifier.scopus2-s2.0-85131125725en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage574en_US
dc.identifier.urihttps://doi.org/10.1016/j.jcis.2022.05.056
dc.identifier.urihttps://hdl.handle.net/20.500.12452/12118
dc.identifier.volume623en_US
dc.identifier.wosWOS:000880650300008en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherAcademic Press Inc Elsevier Scienceen_US
dc.relation.ispartofJournal Of Colloid And Interface Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCatalysisen_US
dc.subjectMagnetic Catalysten_US
dc.subjectMetal Oxideen_US
dc.subjectPalladium Nanoparticlesen_US
dc.subjectSonogashira Cross-Couplingen_US
dc.titleMagnetically separable nickel ferrite supported palladium nanoparticles: Highly reusable catalyst in Sonogashira cross-coupling reactionen_US
dc.typeArticleen_US

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