Novel chiral Tetraazacalix[4]arene[2]triazine-based derivatives as catalysts: enantioselective Michael reaction of nitroolefins and diketones

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dc.contributor.authorGenc, Hayriye Nevin
dc.date.accessioned2024-02-23T13:56:13Z
dc.date.available2024-02-23T13:56:13Z
dc.date.issued2023
dc.departmentNEÜen_US
dc.description.abstractA novel derivatives of tetraazacalix[4] arene[2] triazine-based catalysts for enantioselective Michael addition reactions of nitroolefins and diketones were presented. Chiral moieties were connected to the heteroatom-bridged calix-triazin scaffold by reactions of (S)- or (R)-(+)-1-(1-Naphthyl)ethylamine with tetraazacalix[4]arene[2]triazine. To utilize the catalytic activity of the chiral catalysts, diketones reacted with a wide variety of trans-beta-nitrostyrenes in Toluene, respectively, obtaining the Michael products in excellent yields and enantiomeric excesses (up to 96% yield and 99% ee). [GRAPHICS] .en_US
dc.description.sponsorshipNecmettin Erbakan Universityen_US
dc.description.sponsorshipThis research was financially supported by Necmettin Erbakan University.en_US
dc.identifier.doi10.1007/s10847-023-01186-1
dc.identifier.endpage199en_US
dc.identifier.issn1388-3127
dc.identifier.issn1573-1111
dc.identifier.issue5.Hazen_US
dc.identifier.scopus2-s2.0-85153731177en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage189en_US
dc.identifier.urihttps://doi.org/10.1007/s10847-023-01186-1
dc.identifier.urihttps://hdl.handle.net/20.500.12452/11129
dc.identifier.volume103en_US
dc.identifier.wosWOS:000980489100001en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal Of Inclusion Phenomena And Macrocyclic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAsymmetric Synthesisen_US
dc.subjectMichael Additionen_US
dc.subjectOrganocatalysisen_US
dc.subjectStereoselectivityen_US
dc.subjectTetraazacalix[4]Arene[2]Triazineen_US
dc.titleNovel chiral Tetraazacalix[4]arene[2]triazine-based derivatives as catalysts: enantioselective Michael reaction of nitroolefins and diketonesen_US
dc.typeArticleen_US

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