Novel and highly efficient bifunctional calixarene thiourea derivatives as organocatalysts for enantioselective Michael reaction of nitroolefins with diketones

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dc.contributor.authorGenc, Hayriye Nevin
dc.contributor.authorSirit, Abdulkadir
dc.date.accessioned2024-02-23T13:56:12Z
dc.date.available2024-02-23T13:56:12Z
dc.date.issued2018
dc.departmentNEÜen_US
dc.description.abstractNew bifunctional calixarene thiourea organocatalysts were synthesized and applied in catalytic asymmetric Michael addition of acetylacetone to various nitroolefins at room temperature. The corresponding adducts were obtained in good to excellent yields with excellent enantioselectivities (up to 92% ee). The present research demonstrates the advantages of incorporating two stereocontrolling structures into a single catalyst. Notably, it offers a simple and convenient doubly stereocontrolled approach for the catalytic asymmetric synthesis of a chiral organic molecule.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey [TUBITAK-113Z696]; Research Foundation of Necmettin Erbakan University [BAP-141110003]en_US
dc.description.sponsorshipThe authors gratefully acknowledge the financial support of this work given by the Scientific and Technological Research Council of Turkey (TUBITAK-113Z696) and Research Foundation of Necmettin Erbakan University (BAP-141110003).en_US
dc.identifier.doi10.1007/s10847-017-0761-1
dc.identifier.endpage49en_US
dc.identifier.issn1388-3127
dc.identifier.issn1573-1111
dc.identifier.issue1.Şuben_US
dc.identifier.scopus2-s2.0-85040829208en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage39en_US
dc.identifier.urihttps://doi.org/10.1007/s10847-017-0761-1
dc.identifier.urihttps://hdl.handle.net/20.500.12452/11126
dc.identifier.volume90en_US
dc.identifier.wosWOS:000423143300003en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal Of Inclusion Phenomena And Macrocyclic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCalixarenesen_US
dc.subjectAsymmetric Michael Addition Reactionsen_US
dc.subjectThioureaen_US
dc.subjectOrganocatalysisen_US
dc.subjectEnantioselectivityen_US
dc.titleNovel and highly efficient bifunctional calixarene thiourea derivatives as organocatalysts for enantioselective Michael reaction of nitroolefins with diketonesen_US
dc.typeArticleen_US

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